An experimental and computational study of the formation of (. pi.-allyl) palladium complexes from olefins and palladium (II) salts

…, P Beak, WH Saunders

文献索引：Chrisope,D.R.; Beak,P.; Saunders,W.H. Journal of the American Chemical Society, 1988 , vol. 110, p. 230

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被引用次数: 27

摘要

Conclusions The following conclusions may be derived from this study:(1) X-ray crystallographic work indicates that 1, Zdiphenyl-3-nitrocyclopropene exists as the bisected conformer in the solid state. Ab initio calculations on 3-nitrocyclopropene indicate that this is true for the gas phase as well.(2) The ring bond lengths (long C (l)-C (2), short C (l)-C (3)) and especially the long CN bond length are anomalous for a strong? r-acceptor such as ...