The Journal of Organic Chemistry

Preparation of alkyl 2, 2-dialkoxypropanoates

NE Hoffman, TV Kandathil

文献索引：Hoffman,N.E.; Kandathil,T.V. Journal of Organic Chemistry, 1967 , vol. 32, p. 1615 - 1617

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被引用次数: 3

摘要

Decarbonylation of benzoyl fluoride by tris (tripheny1phosphine) rhodium chloride was observed in reactions carried out either in excess, neat benzoyl fluoride, or using solvents like benzene, toluene, o-xylene, and a-methylnaphthalene. Best results were obtained either in reactions in neat benzoyl fluoride or in o-xylene as solvent. Reactions were carried at 80- 120" heating the reaction mixture for 1 hr, then distilling off products and analyzing by glpc ...