Synthesis and characterization of palladium (II) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low molecular weight …

…, G Czermak, A Dumfort, A Meli, W Oberhauser…

文献索引：Bianchini, Claudio; Brueggeller, Peter; Claver, Carmen; Czermak, Georg; Dumfort, Alexander; Meli, Andrea; Oberhauser, Werner; Suarez, Eduardo J. Garcia Dalton Transactions, 2006 , # 24 p. 2964 - 2973

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被引用次数: 12

摘要

The bis-cationic diphosphonium-diphosphine 6, 7-di (di-2-methoxyphenyl) phosphinyl-2, 2, 4, 4-tetra (di-2-methoxyphenyl)-2λ4, 4λ4-diphosphoniumbicyclo [3.1. 1] heptane-bis (PF6)((o- MeO-PCP)(PF6) 2) and the diphosphine rac-2, 4-bis ((di-2-methoxyphenyl) phosphino) pentane (rac-o-MeO-bdpp) have been synthesized. Both ligands have been employed to coordinate PdCl2 and Pd (OAc) 2 to give [PdCl2 (o-MeO-PCP)](PF6) 2 (1a), PdCl2 (rac-o- ...