Silicon–carbon bond cleavage of organosilicon amines Me n N [CH 2 Si (OCH 2 CH 2) 3 N] 3–n (n= 1, 2) by phenols

NF Lazareva, EI Brodskaya…

文献索引：Lazareva, Nataliya F.; Brodskaya, Esfir I.; Ratovsky, Gennadii V. Journal of the Chemical Society. Perkin Transactions 2, 2002 , # 12 p. 2083 - 2086

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被引用次数: 1

摘要

Anomalously high basicity of organosilicon amines MenN [CH2Si (OCH2CH2) 3N] 3–n determines the ease of nucleophilic cleavage of the Si–C bond by phenols even at room temperature. The conversion of silatrane increases both with phenol acidity and basicity of the exocyclic nitrogen atom.