Journal of the Chemical Society (Resumed)

258. Reactions of aromatic nitro-compounds with alkaline sulphides. Part III. Dinitronaphthalenes

HH Hodgson, ER Ward

文献索引：Hodgson; Ward Journal of the Chemical Society, 1945 , p. 794 Journal of the Chemical Society, 1949 , p. 1187,1189, 1190

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被引用次数: 3

摘要

A dinitronaphthalene reacts with alkali sulphides, and in particular with sodium hydrogen sulphide to form, mainly, a monoamine by reduction, and a sodium mercaptide by replacement of a nitro-with a sodium-thio-(SNa-) group, the ratio of these productsvarying according to the electropositivity of the carbon atom to which the reactive nitro-group is attached. 1: 2-or 1: 8-Dinitronaphthalene gives only mercaptan, whereas the 1: 3-, 1: 5-, 1: ...