Chemical communications

Copper-and palladium-catalyzed intramolecular C–S bond formation: a convenient synthesis of 2-aminobenzothiazoles

LL Joyce, G Evindar, RA Batey

文献索引：Joyce, Laurie L.; Evindar, Ghotas; Batey, Robert A. Chemical Communications, 2004 , # 4 p. 446 - 447

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被引用次数: 87

摘要

Copper-and palladium-catalyzed intramolecular C–S bond formation by cross-coupling between an aryl halide and thiourea functionality is demonstrated for the synthesis of 2- aminobenzothiazoles, wherein the Cu-catalyzed protocol is generally superior and more cost effective than the Pd-catalyzed protocol; the Cu-catalyzed reaction also further expands recent studies exploring the utility of Cu salts as replacements for Pd in carbon– ...