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Tetrahedron Letters

Synthesis, optical, electrochemical, and thermal studies on triazole-based dendrimers with diphenylamine as surface group

P Rajakumar, C Satheeshkumar, S Raja

文献索引:Rajakumar, Perumal; Satheeshkumar, Chinnadurai; Raja, Sebastian Tetrahedron Letters, 2010 , vol. 51, # 39 p. 5167 - 5172

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被引用次数: 12

摘要

Fréchet-type dendrimers with hole-transporting diphenylamine as surface group and electron-transporting triazole moiety as building block have been synthesized by convergent synthetic strategy through 'click chemistry'methodology. First generation dendrimer exhibits longer relaxation time, higher quantum yield in the fluorescence spectrum, and better thermal stability than the zero and second generation dendrimers. CV studies showed ...