Tetrahedron

Polymer-supported palladium catalysed Suzuki–Miyaura reactions in batch and a mini-continuous flow reactor system

NTS Phan, J Khan, P Styring

文献索引：Phan, Nam T.S.; Khan, Jamil; Styring, Peter Tetrahedron, 2005 , vol. 61, # 51 p. 12065 - 12073

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被引用次数: 83

摘要

A polymer-supported palladium (II) salen-type complex exhibited catalytic activity in the cross-coupling reaction of various aryl bromides and heteroaryl bromides with phenylboronic acid in a mini-continuous flow reactor system at elevated temperatures in a phosphine-free system. The reaction was also performed in batch using a number of different solvent systems in order to optimise conditions. The catalytic mini-reactor can be ...