The Influence of Phosphane Ligands on the Versatility of Ruthenium–Indenylidene Complexes in Metathesis

J Broggi, CA Urbina??Blanco, H Clavier…

文献索引：Broggi, Julie; Urbina-Blanco, Cesar A.; Clavier, Herve; Leitgeb, Anita; Slugovc, Christian; Slawin, Alexandra M. Z.; Nolan, Steven P. Chemistry - A European Journal, 2010 , vol. 16, # 30 p. 9215 - 9225

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被引用次数: 44

摘要

Abstract The aim of the present study is to develop readily available and stable pre-catalysts that could be easily prepared on large scale from simple starting materials. Based on the hypothesis that substitution of classical PCy 3 with phosphanes of varying electron-donating properties could be a straightforward manner to improve catalytic activity, a methodical study dealing with the effect of phosphane fine-tuning in ruthenium–indenylidene catalysts was ...