Journal of Organometallic Chemistry

Studies on ylides: Carbonyl olefination with (p-nitro benzylidene) triphenylarsenane

PS Kendurkar, RS Tewari

文献索引：Kendurkar,P.S.; Tewari,R.S. Journal of Organometallic Chemistry, 1973 , vol. 60, p. 247 - 254

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被引用次数: 22

摘要

Abstract (p-Nitrobenzylidene) triphenylarsenane, a semistabilized arsonium ylide has been prepared and reacted with carbonyl compounds to yield olefins as opposed to epoxidation products. Treatment of the ylide with a ranged acyl halides gave new disubstituted arsonium ylides. IR and NMR spectral data for the resulting products are reported.