The Journal of Organic Chemistry

Catalytic and photolytic decomposition of 1-chloro-4-diazoalkenes

RC Atkins, BM Trost

文献索引：Atkins,R.C.; Trost,B.M. Journal of Organic Chemistry, 1972 , vol. 37, p. 3133 - 3139

全文：HTML全文

被引用次数: 3

摘要

The synthesis of l-chloro-4-diazo-2, 3-dimethyl-l-pentene from 3-methyl-3-penten-2-one and of l-chloro-4-diaz0-2~ 3-dimethyl-l-butene from methyl acetoacetate is described. The catalytic decomposition of the diazoalkenes was studied; the decomposition of the latter with mercuric iodide gave l-chloro-2, 3-diniethyl-l, 3-butadi-ene, l-chloro-2-rnethyl-l, 3- pentadiene, and 3-chloro-1, 4-dimethylcyclobutene as major products. The mechanism of ...