Journal of the American Chemical Society

The synthesis of 3', 5'-diiodothyronine

P Block Jr, G Powell

文献索引：Block; Powell Journal of the American Chemical Society, 1942 , vol. 64, p. 1070,1072

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被引用次数: 23

摘要

Summary 1. 4-Crotyloxy-3, 5-dichlorobenzoic acid rearranges without inversion to give 4- crotyl-2, 6-dichlorophenol; the rearrangement does not take place in the presence of dimethylaniline. 2. 4-s-Butyl-2, 6-dichlorophenol and 4-n-butyl-2, 6-dichlorophenol have been synthesized and characterized. An abnormal Fries reaction was observed during the synthetic work. 3. Allyl 2, 6 dichlorophenyl ether rearranges more slowly than 4-crotyloxy-3 ...