Journal of Organometallic Chemistry

Synthesis of rhodium N-heterocyclic carbene complexes and their catalytic activity in the hydrosilylation of alkenes in ionic liquid medium

J Li, J Peng, Y Bai, G Lai, X Li

文献索引：Li, Jiayun; Peng, Jiajian; Bai, Ying; Lai, Guoqiao; Li, Xiaonian Journal of Organometallic Chemistry, 2011 , vol. 696, # 10 p. 2116 - 2121

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被引用次数: 1

摘要

Rhodium complexes bearing N-heterocyclic carbene (NHC) ligands were prepared from bis (η4-1, 5-cyclooctadiene) dichlorodirhodium and 1-alkyl-3-methylimidazolium-2-carboxylate, and the catalytic properties of rhodium complexes prepared in the hydrosilylation of alkenes in ionic liquid media were investigated. It was found that both the catalytic activity and selectivity of the rhodium complexes bearing NHC ligands were influenced by the ...