Tetrahedron letters

Highly efficient chemical fixations of carbon dioxide and carbon disulfide by cycloaddition to aziridine under atmospheric pressure

A Sudo, Y Morioka, E Koizumi, F Sanda, T Endo

文献索引：Sudo, Atsushi; Morioka, Yosuke; Koizumi, Eri; Sanda, Fumio; Endo, Takeshi Tetrahedron Letters, 2003 , vol. 44, # 43 p. 7889 - 7891

全文：HTML全文

被引用次数: 65

摘要

Cycloaddition of aziridine with carbon dioxide was successfully catalyzed by alkali metal halide or tetraalkylammonium halide to give the corresponding 5-membered cyclic urethane, 1, 3-oxazolidin-2-one, selectively. The reaction can be performed at ambient temperature under atmospheric pressure. Analoguous reaction of aziridine with carbon disulfide also successfully gave the corresponding 5-membered cyclic dithiourethane, 1, 3- ...