Inorganic Chemistry

Preparation and proposed structure for bis [bis (dimethylamino) bromoborane]-tris (titanium tetrabromide)

MR Suliman, EP Schram

文献索引：Gmelin Handbook: B: B-Verb.3, 10.4.4.1, page 174 - 175 Show Details Suliman, M. R.; Schram, E. P. Inorganic Chemistry, 1973 , vol. 12, p. 920 - 922

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被引用次数: 2

摘要

Treatment of [(CH,), N], BBr with TiBr, affords {[(CH3), N], BBr),{TiBr4},. The stoichiometry of the latter was established by determination of the reactant ratio and by nucleophilic degradation affording TiBr,. N (CH,), and [(CH,), N], BBr. A structure is proposed for {[(CH,), N], BBr),{TiBr4}, base&on infrared assignments and the unusual stoichiometry of this compound.