Ketonization of the unusually acidic elongated enol generated by flash photolytic decarboxylation of p-formylphenylacetic acid in aqueous solution

Y Chiang, K Kolmakov…

文献索引：Chiang, Yvonne; Kolmakov, Kirill; Kresge, A. Jerry Canadian Journal of Chemistry, 2008 , vol. 86, # 2 p. 101 - 104

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被引用次数: 3

摘要

Rates of photolysis of p-formylphenylacetic acid were measured flash photoytically in perchloric acid and sodium hydroxide solutions, and also in acetic acid, biphosphate ion, and tris-(hydroxymethyl) methaneammonium ion buffers, using H2O and D2O as solvents. The results provide rate profiles and solvent isotope effects, which indicate that photolysis occurs through an elongated enol intermediate. This enol is unusually strongly acidic, by ...