A convergent and enantioselective synthesis of (+)-amurensinine via selective CH and CC bond insertion reactions

UK Tambar, DC Ebner, BM Stoltz

文献索引：Tambar, Uttam K.; Ebner, David C.; Stoltz, Brian M. Journal of the American Chemical Society, 2006 , vol. 128, # 36 p. 11752 - 11753

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被引用次数: 94

摘要

A convergent and enantioselective synthesis of the natural product amurensinine is described. The synthetic strategy takes advantage of mild and selective CH and CC bond insertion reactions, in addition to the palladium-catalyzed aerobic oxidative kinetic resolution recently developed in these laboratories.