Ion-neutral complexes as intermediates in the decompositions of C5H10O2. cntdot.+ isomers

…, CE Hudson, M Skyiepal, E Broido…

文献索引：McAdoo, David J.; Hudson, Charles E.; Skyiepal, Mark; Broido, Ellen; Griffin, Lawrence L. Journal of the American Chemical Society, 1987 , vol. 109, # 25 p. 7648 - 7653

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被引用次数: 22

摘要

Abstract: Ionized pentanoic acid, 3-methylbutanoic acid, and the enol isomer of ionized isopropyl acetate are shown to pass in part through common intermediates before decomposing to CH3CHC (OH) 2+(7) and the" McLafferty+ 1" ion CH3C (OH) 2+(10). The H transfer to form the methyl of CH $(OH),+ and the joining of two CH2 groups to form the CC bond in the ethylene eliminated to produce CH3CHC (OH) 2+ are both attributed to ...