Tetrahedron Letters

Organosilicon radical-induced cyclization reactions

GA Kraus, S Liras

文献索引：Kraus, George A.; Liras, Spiros Tetrahedron Letters, 1990 , vol. 31, # 37 p. 5265 - 5268

全文：HTML全文

被引用次数: 16

摘要

Abstract The first examples of selective additions of organosilicon radicals are reported. Trichlorosilyl radicals preferentially attack the carbonyl oxygen atom, while triethylsilyl radicals preferentially attack alkenes. Carbon-carbon bond formation to produce both monocyclic and bridged bicyclic systems is possible.