The reaction of 1, 2-amino alcohols with carbon dioxide in the presence of 2-pyrrolidone electrogenerated base. New synthesis of chiral oxazolidin-2-ones

MA Casadei, M Feroci, A Inesi, L Rossi…

文献索引：Casadei, M. Antonietta; Feroci, Marta; Inesi, Achille; Rossi, Leucio; Sotgiu, Giovanni Journal of Organic Chemistry, 2000 , vol. 65, # 15 p. 4759 - 4761

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被引用次数: 31

摘要

The heterocyclic derivatives of 1, 2-amino alcohols have often been successfully employed as chiral auxiliaries in asymmetric synthesis. 1 In this context the role played by chiral oxazolidin-2-ones (Evans' chiral auxiliaries) 2 has been particularly significant. These compounds have been used as chiral auxiliaries in a wide range of reactions (aldol, alkylation, Diels-Alder reactions, etc.) directed to the stereoselective synthesis of natural ...