A kinetic and mechanistic study on the oxidation of indole??3??acetic acid by peroxodisulfate

…, M Suresh, V Anbazhagan, S Lavanya…

文献索引：Kalyanasundharam; Chandramohan; Suresh; Anbazhagan; Lavanya; Renganathan International Journal of Chemical Kinetics, 2005 , vol. 37, # 6 p. 355 - 360

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被引用次数: 4

摘要

Abstract The kinetics of oxidation of indole-3-acetic acid (IAA) by peroxodisulfate (PDS) has been carried out in aqueous acetic acid medium. First-order dependence of rate each with respect to [IAA] and [PDS] was observed. The reaction rate was unaffected by added [H+]. Increase of percentage of acetic acid decreased the rate. Variation of ionic strength (μ) had negligible influence on the rate. A suitable kinetic scheme based on these observations ...