Journal of fluorine chemistry

Dehydrohalogenations of cis-and trans-1-bromo-2-flourocyclohexanes

M Hudlicky

文献索引：Hudlicky,H. Journal of Fluorine Chemistry, 1986 , vol. 32, p. 441

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被引用次数: 12

摘要

Abstract Reactions of both diastereomeric vicinal bromofluorocyclohexanes with sodamide, sodium methoxide, potassium tert-butoxide, and triethylamine were studied. cis-1-Bromo-2- fluorocyclohexane eliminated almost exclusively hydrogen bromide giving mainly 1- fluorocyclohexene and a small amount of 3-fluorocyclohexene. trans-1-Bromo-2- fluorocyclohexane eliminated preferentially hydrogen fluoride on treatment with sodamide ...