文献索引：Brook, A. G.; Nyburg, S. C.; Abdesaken, Fereydon; Gutenkunst, Brigitte; Gutenkunst, Gerhard; et al. Journal of the American Chemical Society, 1982 , vol. 104, # 21 p. 5667 - 5672
Abstract: A solid silaethylene, l, l-bis (trimethylsilyl)-2-(trimethylsiloxy)-2-(1-adamanty1)-1- silaethene (Zc), has been isolated from the photolysis of the isomeric acylsilane. The silaethylene was characterized by IR, Raman, UV,'H NMR, 13C NMR, 29Si NMR, and mass spectroscopy and by its ionization potential. The crystal structure shows a slightly twisted molecule with a silicon-carbon double-bond length of 1.764 A. The molecule smokes ...
