Computational and DNMR Analysis of the Conformational Isomers and Stereodynamics of Secondary 2, 2′-Bisanilides

…, M Chiarucci, L Prati, KW Bentley, C Wolf

文献索引：Mazzanti, Andrea; Chiarucci, Michel; Bentley, Keith W.; Wolf, Christian Journal of Organic Chemistry, 2014 , vol. 79, # 8 p. 3725 - 3730

全文：HTML全文

被引用次数: 1

摘要

The conformational preference of 2, 2′-bisanilides was investigated by variable- temperature NMR spectroscopy, NMR titration and diffusion experiments, IR spectroscopy, computational analysis, and X-ray crystallography. The formation of a conformation having the two amide moieties linked by an intramolecular hydrogen bond was detected at low temperatures. The interconversion kinetics of the two conformational species of bisanilide ...