Journal of Chemical Sciences

Silver complexes of 1, 2, 4-triazole derived N-heterocyclic carbenes: Synthesis, structure and reactivity studies

C Dash, MM Shaikh, P Ghosh

文献索引：Dash, Chandrakanta; Shaikh, Mobin M.; Ghosh, Prasenjit Journal of Chemical Sciences, 2011 , vol. 123, # 2 p. 97 - 106

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被引用次数: 11

摘要

Abstract Two silver (I) complexes {[1-R-4-(Nt-butylacetamido)-1, 2, 4-triazol-5-ylidene] 2 Ag}+ Cl−[R= Et (1b), i-Pr (2b)] of N/O-functionalized N-heterocyclic carbenes derived from 1, 2, 4-triazoles are reported. The silver complexes, 1b and 2b, have been synthesized from the reaction of the N/O-functionalized triazolium chloride salts namely, 1-R-4-(Nt- butylacetamido)-1, 2, 4-triazolium chloride [R= Et (1a), i-Pr (2a)] by treatment with Ag 2 O ...