Trans-2, 6-bis [(dimethylamino) methyl] phenyl-N, N', C complexes of palladium (II) and platinum (II). Crystal structure of [PtI [MeC6H3 (CH2NMe2) 2-o, o']] BF4: a …

DM Grove, G Van Koten, JN Louwen…

文献索引：Grove, David M.; Koten, Gerard van; Louwen, Jaap N.; Noltes, Jan G.; Spek, Anthony L.; Ubbels, Henk J. C. Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6609 - 6616

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被引用次数: 190

摘要

Conclusions Decarboxylation of OPA and other a-keto (3-carboxy carboxylic acids is catalyzed by metal ions through the formation of the bidentate metal chelate, ML, involving the a-keto acid functions. A high formation constant of the metal chelate does not necessarily indicate that the rate of decarboxylation will be increased. Although an increase in the magnitude of the stability constant results in greater conversion of the substrate to the ...