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Journal of the American Chemical Society

Covalent heterogenization of a discrete Mn (II) bis-phen complex by a metal-template/metal-exchange method: An epoxidation catalyst with enhanced reactivity

TJ Terry, TDP Stack

文献索引:Terry, Tracy J.; Daniel; Stack Journal of the American Chemical Society, 2008 , vol. 130, # 14 p. 4945 - 4953

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被引用次数: 69

摘要

Considerable attention has been devoted to the immobilization of discrete epoxidation catalysts onto solid supports due to the possible benefits of site isolation such as increased catalyst stability, catalyst recycling, and product separation. A synthetic metal-template/metal- exchange method to imprint a covalently attached bis-1, 10-phenanthroline coordination environment onto high-surface area, mesoporous SBA-15 silica is reported herein along ...