Radical reactions using decacarbonyldimanganese under biphasic conditions

…, PT McGrail, AF Parsons

文献索引：Huther, Nathalie; McGrail, P. Terry; Parsons, Andrew F. European Journal of Organic Chemistry, 2004 , # 8 p. 1740 - 1749

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被引用次数: 14

摘要

Abstract Radical reactions of alkyl halides, initiated by photolysis in the presence of decacarbonyldimanganese, can be performed in biphasic media. Reactions in the presence of aqueous sodium hydroxide together with a phase-transfer catalyst result in the efficient removal of manganese halide by-products and also lead to the regeneration of decacarbonyldimanganese. A range of efficient radical couplings, cyclisations and ...