Catalytic enantioselective thioester aldol reactions that are compatible with protic functional groups
D Magdziak, G Lalic, HM Lee, KC Fortner…
文献索引：Magdziak, Derek; Lalic, Gojko; Lee, Hong Myung; Fortner, Kevin C.; Aloise, Allen D.; Shair, Matthew D. Journal of the American Chemical Society, 2005 , vol. 127, # 20 p. 7284 - 7285
Catalytic enantioselective aldol reactions of carboxylic acid derivatives have undergone continuous development over the last 20 years. 1 An important recent advance was reported by Evans and co-workers who achieved Ni(II) bis(oxazoline)-catalyzed enantioselective imide aldol reactions with in situ enolate formation in the presence of enolizable aldehydes. 2,3 Our interest in the reactivity of malonic acid half thioesters (MAHTs) led to the discovery that MAHTs can be ...
