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Studies on the Synthesis of a Spiroepoxy Ketal1

KR Huffman, DS Tarbell

文献索引:Huffman; Tarbell Journal of the American Chemical Society, 1958 , vol. 80, p. 6341,6345

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被引用次数: 3

摘要

Treatment of 2-benzhydrylidenetetrahydrofuran with perbenzoic or perphthalic acid does not yield the expected spiroepoxy ketal. Action of t-butyl hypochlorite or N-bromosuccininimide on the benzhydrylidenetetrahydrofuran does not give the corresponding halohydrin, but leads to 2, 2-diphenyl-3-ketotetrahpdropyran by a rearrangement involving ring enlargement. Treatment of ethyl a-propionylpropionate with ethylene chlorohydrin and ...