Electronic Effects in Elimination Reactions. V. The E2 Reaction of β-Phenylethyl Fluorides and Chlorides1, 2

CH DePuy, CA Bishop

文献索引：DePuy,C.H.; Bishop,C.A. Journal of the American Chemical Society, 1960 , vol. 82, p. 2535 - 2537

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被引用次数: 36

摘要

253G CH DEPUY AND CA BISHOP Vol. 82 hydrogen and carbon-halogen bond breaking. 1~~ s 6 It seems clear that the leaving group may influence the reaction electronically in at least two ways; oiz., inductively by acidifying the p-hydrogen and consequently making its removal easier (;. e., I), and by synchronous bond breaking so that the negative charge is removed from the molecule