Journal of the American Chemical Society

Small-Ring Organosilicon Compounds. II. 2: 3-Benzo-1, 1-diphenyl-1-silacyclobut-2-ene

H Gilman, WH Atwell

文献索引：Gilman,H.; Atwell,W.H. Journal of the American Chemical Society, 1964 , vol. 86, p. 5589 - 5593

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被引用次数: 29

摘要

Iv AgN03-C&N spectrum of this material was found to be identical with that of an authentic specimen of X prepared by the reaction of diphenyl-0-tolylsilane (IV) with an aqueous silver nitrate-pyridine mixture. l 1 Compound I is readily cleaved by phenyllithium to give, subsequent to acid hydrolysis, o-tolyltriphenylsilane (XI). 12 None of the ring-opened product XI could be isolated from I and phenylmagnesium bromide at room temperature. ...