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Crown cation complex effects. 20. Syntheses and cation binding properties of carbon-pivot lariat ethers

DM Dishong, CJ Diamond, MI Cinoman…

文献索引:Dishong, Dennis M.; Diamond, Craig J.; Cinoman, Michael I.; Gokel, Geoge W. Journal of the American Chemical Society, 1983 , vol. 105, # 3 p. 586 - 593

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被引用次数: 159

摘要

Abstract: In an effort to devise synthetic cation binders that will mimic the behavior of naturally occurring ionophores such as valinomycin, we have prepared approximately 30 macrocylic (crown) polyethers bearing flexible side chains attached to the macro ring at carbon. In many of these “carbon-pivot” compounds, the side chain contains one or more neutral donor groups that, if in a suitable geometrical arrangement, may provide additional ...

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