Novel and convenient method for the stereo-and regiospecific synthesis of conjugated alkadienes and alkenynes via the palladium-catalyzed cross-coupling reaction …
N Miyaura, K Yamada, H Suginome…
文献索引：Miyaura, Norio; Yamada, Kinji; Suginome, Hiroshi; Suzuki, Akira Journal of the American Chemical Society, 1985 , vol. 107, # 4 p. 972 - 980
Abstract: Details of a new and general method for the stereo-and regiospecific synthesis of conjugated alkadienes and alkenynes are described. The reaction of (E)-or (Z)-1- alkenyldisiamylboranes, or 2-((E)-l-alkenyl)-l, 3, 2-benzodioxaboroles readily obtainable by hydroboration, with either (E)-or (Z)-1-alkenyl bromides in the presence of a catalytic amount of tetrakis-(tripheny1phosphine) palladium and bases such as sodium alkoxides gives the ...
