Formyl cyanide: a stable species. Experimental and theoretical studies
W Lewis-Bevan, RD Gaston, J Tyrrell…
文献索引：Lewis-Bevan, Wyn; Gaston, Rick D.; Tyrrell, James; Stork, Wilmer D.; Salmon, Gary L. Journal of the American Chemical Society, 1992 , vol. 114, # 6 p. 1933 - 1935
Abstract: Formyl cyanide has been generated by the retro-ene cleavage of cinnamyloxyacetonitrile using flash vacuum pyrolysis. Isolation of pure formyl cyanide in the gas phase has shown that the compound is much more stable than originally reported, with a measured half-life of 45.5 h under our experimental conditions. Formyl cyanide readily reacts with water to form hydrogen cyanide and formic acid. The observed vibrational ...
