Tetrahedron Letters

The allyloxycarbonylaminomethyl group: a new allytic protection for the thiol group of cysteine

AM Kimbonguila, A Merzouk, F Guibé, A Loffet

文献索引：Kimbonguila, Andre Malanda; Merzouk, Ahmed; Guibe, Francois; Loffet, Albert Tetrahedron Letters, 1994 , vol. 35, # 48 p. 9035 - 9038

全文：HTML全文

被引用次数: 12

摘要

Abstract S-Allocam derivatives of thiols in general and cysteine in particular are selectively and readily deprotected through palladium catalyzed hydrostannolysis. They are perfectly stable in the basic conditions of Fmoc-removal, but only marginally stable in the acidic conditions of t-Bu, Boc removal.