Bulletin of the Chemical Society of Japan

Metal-catalyzed organic photoreactions. The photooxidation of olefins in the presence of uranyl acetate.

E Murayama, T Sato

文献索引：Murayama,E.; Sato,T. Bulletin of the Chemical Society of Japan, 1978 , vol. 51, p. 3022 - 3026

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被引用次数: 12

摘要

The photooxidation of olefins in pyridine in the presence of uranyl acetate afforded β- hiydroxy hydroperoxides. It was confirmed by spectroscopic studies and isotope- incorporation experiments that (1) the stereochemistry of the hydroxyl and hydroperoxyl groups in the β-hiydroxy hydroperoxides was trans,(2) the hydroxyl group was added to the less substituted carbon of the double bond, and (3) the oxygen atom in the hydroxyl group ...