Tetraazapentalene Chemistry: Unexpected Intramolecular Electron Rearrangement Induced by Highly Reactive ψ??Dinitroso Substituents

MHV Huynh, MA Hiskey, DE Chavez…

文献索引：Huynh, My Hang V.; Hiskey, Michael A.; Chavez, David E.; Gilardi, Richard D. Angewandte Chemie - International Edition, 2005 , vol. 44, # 43 p. 7089 - 7094

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被引用次数: 10

摘要

Tetraazapentalenes (TAP),[1–4] tetraazaphosphapentalenes (TAPP),[5] tetraazathiapentalenes (TATP),[6–7] tetraazaselenapentalenes (TASP),[8–9] and their derivatives (Scheme 1) are of special interest owing to their unusual electronic structure and chemical behavior which is governed by the striking orientations of the heteroatoms. These heterocyclic systems promise a variety of applications including in organic synthesis, ...