Polyhedron

Synthesis and characterization of some zinc, cadmium and mercury (II) derivatives of bis (4-methylpyrazol-1-yl) alkanes

C Pettinari, C Santini, D Leonesi, P Cecchi

文献索引：Pettinari, C.; Santini, C.; Leonesi, D.; Cecchi, P. Polyhedron, 1994 , vol. 13, p. 1553 - 1562

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被引用次数: 32

摘要

Abstract The interaction between bis (4-methylpyrazol-1-yl) methane, L, and various MX 2 (M= Zn, X= Cl, Br or I; M= Cd, X= Cl, I or NO 3; M= Hg, X= Cl, Br, I, CN or SCN) gives the 1: 1 adducts [L] MX 2, which are air-and thermally stable. The ligand also gives 2: 1 {[L] 2 Zn (CF 3 SO 3) 2· 2H 2 O,[L] 2 Zn (NO 3) 2· 3H 2 O,[L] 2 Cd (ClO 4) 2· H 2 O,[L] 2 Hg (CF 3 CO 2) 2} and 3: 1 {[L] 3 Zn (ClO 4) 2,[L] 3 Zn (BF 4) 2,[L] 3 Zn (CF 3 CO 2) 2· H 2 O,[L] 3 Cd (BF 4) 2· ...