Preparation and Determination of Apparent Dissociation Constants of Some Alkylphosphonic and Dialkylphosphinic Acids1

PC Crofts, GM Kosolapoff

文献索引：Crofts; Kosolapoff Journal of the American Chemical Society, 1953 , vol. 75, p. 3379,3382

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被引用次数: 139

摘要

The apparent dissociation constants An approximately linear relationship was found between the number of observations were made relative to the isolation and purification of these substances. Grignard reagents react with phosphorus trichloride only to the stage of disubstitution. of the acids were determined potentiometrically. methyl groups attached to a specific carbon in the alkyl group and the magnitude of pK'.