Tetrahedron

Disubstituted “K-region” arene oxides

D Avnir, A Grauer, D Dinur, J Blum

文献索引：Avnir,D. et al. Tetrahedron, 1975 , vol. 31, p. 2457 - 2459

全文：HTML全文

被引用次数: 8

摘要

The first syntheses of tri-and tetra-cyclic vic-disubstituted arene oxides are described. The general route to 9, 10-dimethyl-and 9, 10-bis (p-chlorophenyl)-phenanthrene-9, 10-oxide, and to 5, 6-diphenylbenzo [c] phenanthrene 5, 6-oxide, includes oxidation of the unsubstituted aromatic hydrocarbon to the K-region quinone followed by reaction with an alkyl-or aryl-magnesium bromide and treatment of the resulting trans-diol with ...