前往化源商城

Olefin Cyclopropanation by a Sequential Atom??Transfer Radical Addition and Dechlorination in the Presence of a Ruthenium Catalyst

K Thommes, G Kiefer, R Scopelliti…

文献索引:Thommes, Katrin; Kiefer, Gregor; Scopelliti, Rosario; Severin, Kay Angewandte Chemie - International Edition, 2009 , vol. 48, # 43 p. 8115 - 8119

全文:HTML全文

被引用次数: 37

摘要

Cyclopropanes can be found in a number of biologically active compounds, and methods for the synthesis of this smallest carbocycle have been investigated extensively.[1] Most often, cyclopropanations are performed with Simmons–Smith-type reagents or by transition metal catalyzed reactions of olefins with diazo compounds.[1] Cyclopropanes can also be synthesized by reductive coupling of 1, 3-dihalogen derivatives. Reagents, which can ...