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The Journal of Organic Chemistry

Cyclopropylcarbinyl-allylcarbinyl radical rearrangements in the benzobicyclo [4.1. 0] heptene system

EC Friedrich, RL Holmstead

文献索引:Friedrich,E.C.; Holmstead,R.L. Journal of Organic Chemistry, 1972 , vol. 37, # 16 p. 2546 - 2550

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被引用次数: 22

摘要

Preparation of benxobicyclo [4.1. 0] hept-&ene, and a study of its light-initiated free-radical bromination using AY-bromosuccinimide in carbon tetrachloride, is reported. Also, an investigation of the free-radical tri-n-butyltin hydride reduction of 2-bromomethyl-l, Qdihydronaphthalene was carried out. In both the bromination and tin hydride reduction studies in the benxobicyclo [4.1. 0] heptenyl system, examination of the product ...