Molybdenum (IV) Complexes as Efficient, Lewis Acidic Catalysts for Allylic Substitution. Formation of CC and CN Bonds

…, P Spoor, V Vinader, P Kočovský

文献索引：Malkov, Andrei V.; Spoor, Paul; Vinader, Victoria; Kocovsky, Pavel Journal of Organic Chemistry, 1999 , vol. 64, # 14 p. 5308 - 5311

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被引用次数: 54

摘要

In transition-metal-catalyzed allylic substitution (Scheme 1), allylic acetates and carbonates play a prime role as electrophilic substrates. Numerous studies and applications using Pd (0), 1 Mo (0), 2 and W (0) 3 complexes and a variety of reacting partners show how general this reaction is. Although the literature in this area is dominated by CC bond-forming processes, examples of CN, CO, C-Cl, and CS bond construction have also been reported ...