The Journal of Organic Chemistry

Rearrangement of the 1, 2, 2-Triphenylethyl Radical

WA Bonner, FD Mango

文献索引：Bonner,W.A.; Mango,F.D. Journal of Organic Chemistry, 1964 , vol. 29, p. 29 - 34

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被引用次数: 6

摘要

2, 3, 3-Triphenylpropionaldehyde has been prepared by the lithium aluminum hydride reduction of N-(2, 3, 3-triphenylpropiony1) azridine. The t-butyl peroxide-catalyzed decarbonylation of this aldehyde in o-dichlorobenzene solvent at 155-185" yielded monomeric product, s (15'%), consisting of l, l, Ztriphenylethane (957,) and triphenylethylene (57&), and a dimeric product (857,) whose infrared and n. nI. r. spectra were in accord with ...