Inorganica Chimica Acta

Cyclopalladation of N-phenylbenzamides: Synthesis and structure of bimetallic palladium (II)-complexes

N Borduas, AJ Lough, VM Dong

文献索引：Borduas, Nadine; Lough, Alan J.; Dong, Vy M. Inorganica Chimica Acta, 2011 , vol. 369, # 1 p. 247 - 252

全文：HTML全文

被引用次数: 15

摘要

Three bimetallic palladium (II) complexes were generated by cyclopalladation of N-methyl-N- phenylbenzamide derivatives, substrates known to undergo oxidative intramolecular cross- coupling via palladium catalysis. These isolable Pd-complexes were characterized by X-ray crystallography. Stoichiometric and catalytic experiments with [(3-methoxy-N-methyl-N- phenylbenzamide) Pd (μ-TFA)] 2 were investigated, and this palladium complex was ...