Journal of fluorine chemistry

A well feasible and general route to (organoethynyl) difluoroboranes, RHC CBF 2, and their perfluorinated analogues, RFC CBF 2

VV Bardin, NY Adonin, HJ Frohn

文献索引：Bardin, Vadim V.; Adonin, Nicolay Yu.; Frohn, Hermann-Josef Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 699 - 702

全文：HTML全文

被引用次数: 14

摘要

A representative series of (organoethynyl) difluoroboranes RCCBF2 (RC4H9,(CH3) 3C, CF3, C3F7,(CF3) 2CF, CF3CFCF, C4F9CFCF, C6F5) was prepared by abstraction of fluoride from the corresponding K [RCCBF3] salts with BF3 in appropriate solvents (1, 1, 1, 3, 3-pentafluoropropane, 1, 1, 1, 3, 3-pentafluorobutane, or dichloromethane).