Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Phenylisocyanate and phenylthioisocyanate react with Grignard reagents in the presence of a small amount of Cp 2 TiCl 2 at room temperature to afford reduction-coupling products, N-methyl-N, N′-diphenylurea and N-methyl-N, N′-diphenylthiourea.
[Foreman, Mark St. John; Mortimer, Roger J.; Slawin, Alexandra M. Z.; Woollins, J. Derek Journal of the Chemical Society - Dalton Transactions, 1999 , # 19 p. 3419 - 3430]