Journal of fluorine chemistry

Preparation of trifluoromethylated allylic alcohols from trifluoroacetaldehyde and organometallic compounds

N Ishikawa, GK Moon, T Kitazume, KC Sam

文献索引：Ishikawa, Nobuo; Koh, Moon Gyu; Kitazume, Tomoya; Choi, Sam Kwon Journal of Fluorine Chemistry, 1984 , vol. 24, p. 419 - 430

全文：HTML全文

被引用次数: 43

摘要

Abstract A number of allylic alcohols bearing a trifluoromethyl group at the α-or γ-position, and α-trifluoromethylated γ-enols and-ynols were prepared by the reaction of trifluoroacetaldehyde with a variety of organometallic compounds. Most of the Reformatsky- or Grignard-type reactions required promotion by ultrasonic irradiation.