Phosphonic Acids. VII. The Reaction of Sodium Diethyl Phosphonate with Organic Disulfides

RG Harvey, HI Jacobson…

文献索引：Harvey,R.G. et al. Journal of the American Chemical Society, 1963 , vol. 85, p. 1623 - 1626

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被引用次数: 18

摘要

Sodium diethyl phosphonate in tetrahydrofuran solution reacts rapidly with organic disulfides to produce a phosphorothioate ester and a sodium mercaptide. From ethyl disulfide and &acetamidoethyl disulfide the respective products are O, O, S-triethyl phosphorothioate and 0, O-diethyl Sp. acetamidoethyl phosphorothioate. Reaction with phenyl ethyl disulfide takes place in one direction only to form 0.0, s-triethyl ...